
Organic reagents can be classified as either 有机试剂可分为以下两类:
1. Nucleophiles: Attack centres of low electron density (nucleus loving). They possess a lone pair of electrons and are usually negatively charged.
1. 嗜核者。攻击电子密度低的中心(爱护核子)。它们拥有一对孤独的电子,通常带负电。
Examples include: H2O, ROH, OH-, RO-, Br-, NH3, RNH2, CN-.
2. Electrophiles: Attack centres of high electron density (electron loving) The are capable of accepting a lone pair of electrons and are usually positively charged.
2. 亲电体。高电子密度的攻击中心(热爱电子) 能够接受孤对电子,通常带正电。
Examples include: H+, Br+, R-N=N, CN-.
The properties of an organic molecule are predominately determined by the properties of the functional group in that compound. Functional groups are atoms or combinations of atoms such as OH-, -COOH.
一个有机分子的特性主要由该化合物中的官能团的特性决定。官能团是原子或原子的组合,如OH-、-COOH。
Once the properties of the functional groups are known then the properties of any molecule containing a functional group maybe predicted.
一旦知道了官能团的特性,就可以预测任何含有官能团的分子的特性。
The common functional groups are listed below:










Homologus series: This is a series of compounds in which all the members are similar in constitution (i.e. they contain the same functional group, if any) and therefore in chemical properties.
同系物系列:这是一个化合物系列,其中所有成员在结构上是相似的(即它们包含相同的官能团,如果有的话),因此在化学性质上也是相似的。
Each homologous series has a general formula (e.g. CnH2n+2 for the alkanes) and each member of the series differs from the next by CH2 unit in all cases.
There is a regular change in physical properties as one ascends the series for example: methane - gas, octane - liquid, and higher alkanes - solid.
每个同源系列都有一个一般的公式(例如,CnH2n+2为烷烃),并且在所有情况下,该系列的每个成员都与下一个成员有CH2单元的不同。
随着系列的上升,物理性质有规律的变化,例如:甲烷--气体,辛烷--液体,而更高的烷烃--固体。